Enantioselective epoxidation of 1-hexene with sugar derived hydroperoxides
نویسندگان
چکیده
منابع مشابه
Anomeric Hydroperoxides; Synthesis, Enantioselective Epoxidation
Some time ago we reported the oxidation of 2,3-unsaturated hexopyranosides and 2-Cmethylene glycosides with hydrogen peroxide in the presence of molybdenum trioxide catalyst to give the corresponding anomeric hydroperoxides 1-5. Relatively stable hydroperoxides 1-5 were used for enantioselective oxidation of prochiral alcohols and sulfides in the presence of Ti(OiPr)4 with stereoselectivities v...
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ژورنال
عنوان ژورنال: Arkivoc
سال: 2006
ISSN: 1551-7012
DOI: 10.3998/ark.5550190.0008.903